The absolute temperature scale, specifically Kelvin, is employed in gas law calculations. This scale begins at absolute zero, the theoretical point at which all molecular motion ceases. Using Kelvin ensures that temperature values are always positive, which is mathematically crucial for the validity of gas law equations. For example, a temperature in Celsius must be converted to Kelvin by adding 273.15 before being used in the ideal gas law (PV=nRT).
The use of an absolute temperature scale is essential because the gas laws describe relationships between pressure, volume, temperature, and the amount of gas. Temperature, when expressed in Celsius or Fahrenheit, can take on negative values, leading to nonsensical results when plugged into these equations. Kelvin provides a consistent and physically meaningful basis for quantifying thermal energy within the system, making it possible to accurately predict and describe gas behavior.